Volume 1, Issue 4, October 2013, Page: 49-52
Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base
KHALIL KHALAF ABID, Department of Chemistry, College of Science, Al – Mustanseriyah University, 10053 Baghdad Iraq
Received: Sep. 24, 2013;       Published: Oct. 30, 2013
DOI: 10.11648/j.ajac.20130104.11      View  3040      Downloads  135
Abstract
A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine, benzoyl aceton and metal ion as template effect in the molar ratio of 2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.
Keywords
Macrocyclic, Schiff Bases, Lanthanide Complexes, Template Synthesis
To cite this article
KHALIL KHALAF ABID, Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base, American Journal of Applied Chemistry. Vol. 1, No. 4, 2013, pp. 49-52. doi: 10.11648/j.ajac.20130104.11
Reference
[1]
P. A. Vigato and S. Tamburini; Coord. Chem. Rev., 248 (2004) 1717.
[2]
P. A. Vigato, S. Tamburini and L. Bertolo; Coord. Chem. Rev., 251 (2004) 1311.
[3]
W. Radecka-Paryzek, V. Patroniak and J. Lisowski; Coord. Chem. Rev., 249 (2005) 2156.
[4]
H. Karsilayan, I. Hemmila, H. Takalo, A. Toivonen, K. Pettersson, T. Lovgren and V-M. Mukkala; Bioconjugate Chem., (1997) 871.
[5]
M. Li and P. Selvin; Bioconjugate Chem., 8 (1997) 127.
[6]
R. B. Lauffer; Chem. Rev., 87 (1987) 901.
[7]
S. Aime, M. Botta, M. Fasano and E. Terreno; Acc. Chem. Res., 32 (1999) 941.
[8]
P. H. Smith, J. R. Brainard, D. E. Morris, G. D. Jarvinen and R. R. Ryan; J. Am. Chem. Soc., 111 (1989) 7437.
[9]
K. Kolasa, A. Sharma and J. R. Morrow; Inorg. Chem., 32 (1993) 3983.
[10]
L. L. Chappell, D. A. Voss Jr., W. DeW. Horrocks Jr. and J. R. Morrow; Inorg. Chem., 37 (1998) 3989.
[11]
S. Amin, D. A. Voss Jr, W. DeW. Horrocks Jr. and J. R. Morrow; Inorg. Chem., 35 (1996) 7466.
[12]
J. R. Morrow;" Metal Ions in Biological Systems" (1996) 33H, Sigel (Ed.) Dekker, New York, pp. 561–591.
[13]
A. De Mesmaeker, R. Haner, R. P. Martin, H. E. Moser; Acc. Chem. Res.,28 (1995) 366.
[14]
D. Magda, M. Wright, S. Crofts, A. Lin and J. L. Sessler; J. Am. Chem. Soc.,119 (1997) 6947.
[15]
J. R. Morrow, L. A. Buttrey, V. M. Shelton and K. A. Berback; J. Am. Chem. Soc., 114 (1992) 1903.
[16]
J. Lisowski and P. Starynowicz; Polyhedron,18 (1998) 443.
[17]
E. Spodine, Y. Moreno, M.T. Garland,O. Pena and R. Baggio; Inorg. Chim. Acta,30 (2000) 957
[18]
S. Chandrai, M. Tyagi and S. Agrawalj; Serb. Chem. Soc. 75 (7) (2010) 935
[19]
S. S. Nivasan and P. Athappan ; Transition Met. Chemistry, 26 (2001) 588
[20]
C. Lodeiro, R. Basitida, E. Bertolo, A. Macias and R. Rodriguez ; Transition Met. Chemistry, 28 (2003) 388.
[21]
V. B. Rana, J. N. Gurtu and M. P. Teotia; Indian J. Chem., 19A (1980) 133.
[22]
P. K. Sasmal , S. Saha , R. Majumdar and R. Dighe ; Inorg. Chem., 49(3) (2010) 849.
[23]
M. R. Maurya, A. Kumar, A. R. Bhat, A. R. Azam, A. Bader and D. Rehder ; Inorg. Chem., 45(3) (2006) 1260.
[24]
T. Szczurek, and M. Schlesinger" Rare Earth Spectroscopy" World Scientific, Singapore (1985) p309
[25]
M. H. V. Werts ; Science Progress, 88 (2005) 101.
[26]
N. Greenwood and A. Earnshaw;"Chemistry of the Elements " (1997) p 1242, 2ndedition, Butterworth – Heinmann. ISBN 0080379419.
Browse journals by subject