Volume 2, Issue 1, February 2014, Page: 10-14
Synthesis of a Biobased Antioxidant Additive for Diesel Fuel
Chikh Sabrina, Laboratory of Petrochemical synthesis, Faculty of Hydrocarbons and Chemistry, University M’hamed Bouguara-Boumerdes, Algeria
Pemanos Yelda Bakoz, Depatment of Chemistry, College of Science, University of ZaKho, Kurdistan Rigion, Iraq
Zourane Tinhinane, Laboratory of Petrochemical synthesis, Faculty of Hydrocarbons and Chemistry, University M’hamed Bouguara-Boumerdes, Algeria
Hamada Boudjema, Laboratory of Petrochemical synthesis, Faculty of Hydrocarbons and Chemistry, University M’hamed Bouguara-Boumerdes, Algeria
Received: Feb. 5, 2014;       Published: Mar. 10, 2014
DOI: 10.11648/j.ajac.20140201.13      View  2560      Downloads  175
Abstract
In this study, our objective is to synthesize a biobased antioxidant additive for Diesel fuel during the storage. Our choice was made particularly on the olive oil as raw material because of its oleic acid content which is more to 75%. The processes involved were epoxidation of oleic acid of the olive oil, opening of the oxirane ring, and esterification. The structures of the products were confirmed by FTIR. To test the effectiveness of our biobased antioxidant additive, we carried out Accelerated Oxidation Test – AOT on diesel without additive (blank) and diesel with additive with various concentrations: 2000,4000 and 6000 ppm. The oxidative degradation of diesel with or without antioxidants was investigated by UV-visible spectroscopy was used to monitor the changes using peroxide value. A remarkable stability of diesel with antioxidant additive comparing with the blank confirms the inhibition of the oxidation phoneme and thus of the good efficiency of antioxidant additive from the optimal concentration of 2000ppm.
Keywords
Biobased Additive, Antioxidant, Diesel Fuel, Peroxide Value, Accelerated Oxidation Test
To cite this article
Chikh Sabrina, Pemanos Yelda Bakoz, Zourane Tinhinane, Hamada Boudjema, Synthesis of a Biobased Antioxidant Additive for Diesel Fuel, American Journal of Applied Chemistry. Vol. 2, No. 1, 2014, pp. 10-14. doi: 10.11648/j.ajac.20140201.13
Reference
[1]
N.Salih, J.Salimon and E. Yousif, "Synthetic biolubricant basestocks based on environmentally friendly raw materials", Journal of King Saud University – Science (2012) 24, 221–226.
[2]
M.Senthil Kumar, A.Ramesh and B.Nagalingam, "Biomass and bio-energy" (2003) 25, 309.
[3]
M.Eissen,J.Metzger,E.Schmidt,U. Schneidewind, "10 years after Rio - Concepts on the contribution of chemistry to a sustainable development, Angew". Chem. Int. Ed (2002) 41, 414-436.
[4]
M.Genas, Rilsan (Polyamid 11), "Synthese and Eigenschaften, Angewandte Chemie", (1962)74,535-540.
[5]
J.C. Guibet, "Carburants et moteurs: technologies, énergie, environnement" ,Volume 1 (1994).
[6]
D.Chaithongdee,J.Chutmanop,P.Srinophakun, "Effect of Antioxidants and Additives on the Oxidation Stability of Jatropha Biodiesel". Kasetsart Journal – Natural Science (2010) 44, 243-50.
[7]
M.L.A.Tavares, N.Queiroz,I.M.G .Santos, A. L.Souza,E. H. S.Cavalcanti, A. K. D. Barros, R.Rosenhaim, L. E. B.Soledade, A. G. Souza, "Sunflower Biodiesel. Use of P-DSC in the Evaluation of Antioxidant Efficiency". Journal of Thermal Analysis and Calorimetry (2011) 106(2), 575-9.
[8]
L. R.Almeida, A. L.Silva, F. H. N.Souza, A. A. Hidalgo, M. L.Vega, H. N.Cunha, M. A. S. Rios, "Evaluation of Antioxidant Potentiality of Compounds Derived from Biomass for Application in Biodiesel from Soybean Oil", Química no Brasil, (2011).
[9]
H. N. Fernando Souza, R.de Almeida Layane, C. L. Batista Francisco Samuel, Alexsandra de S. Rios Maria, "UV-Visible Spectroscopy Study of Oxidative Degradation of Sunflower Biodiesel",CSCanada Energy Science and Technology Vol. 2, (2011), pp. 56-61.
[10]
J.Salimon, N.Salih, E.Yousif, "Chemically modified biolubricant basestocks from epoxidized oleic acid: Improved low temperature properties and oxidative stability",Journal of Saudi Chemical Society (2011) 15, 195–201.
[11]
Tayde Saurabh., M.b.Patnaik, S.L. Bhagt, V.C. Renge, "Epoxidation of vegetable oils", International journal of advanced engineering technology, a review (2011) 0976-3945.
[12]
Z.S.Petrovic, A. Zlatanic , C.C. Lava , S. Sinadinovicfise , "Epoxidation of soya bean oil in toluene with peroxoacetic acid and peroxoformic acids-kinetics and side reactions". European Journal of Lipid Science and Technology (2002). 104(5):293-299.
[13]
S.F.Snezana, J.Milovan, S.P.Zoran. "Kinetics of in situ Epoxidation of Soybean Oil in Bulk Catalyzed by Ion Exchange Resin" JAOCS, Vol1, (2001). 78, no. 7
[14]
N. Salih, J. Salimon, E.Youcef, "Synthesis of oleic acid based esters as potential basestock for biolubricant production". Turkish J. Eng. Env. Sci. (2011) 35, 115 – 123.
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