Volume 2, Issue 1, February 2014, Page: 15-18
Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal
Ali Mohammed Yimer, Department of Applied Chemistry, College of Natural and Computational Sciences, Arba Minch University (Ethiopia)
T. Baraki, Department of Chemistry, College of Natural and Computational Sciences, Hramaya University (Ethiopia)
R. K. Upadhyay, Department of Chemistry, College of Natural and Computational Sciences, Hramaya University (Ethiopia)
Masood Akhtar, Department of Applied Chemistry, College of Natural and Computational Sciences, Arba Minch University (Ethiopia)
Received: Feb. 19, 2014;       Published: Mar. 20, 2014
DOI: 10.11648/j.ajac.20140201.14      View  2737      Downloads  128
Abstract
The Cr(III), Fe(III), Co(II), Ni(II), Cu(II) and Zn(II) complexes with a novel tetradentate ligand obtained by condensation of ethylenediamine with ortho-hydroxyphenylglyoxal have been synthesized and characterized by elemental analysis, molar conductance and magnetic susceptibility measurements, IR, UV-Visible and atomic absorption studies. The Cr(III), Fe(III) and Co(II) complexes possess six coordinate octahedral geometry whereas Ni(II), Cu(II) and Zn(II) complexes are square planar and tetrahedral respectively. Bactericidal and fungicidal activities of the compounds were evaluated in vitro by disc diffusion method. The perusal of antimicrobial activities of the compounds reveals that the complexes possess greater bactericidal and fungicidal activities against all the microbes in comparison to ligand which is due to their higher lipophilicity.
Keywords
Bactericidal and Fungicidal Activities, Ortho-Hydroxyphenylglyoxal, Thin-Layer Chromatography, Structural Geometry, Lipophilicity, Tetradentate Ligand
To cite this article
Ali Mohammed Yimer, T. Baraki, R. K. Upadhyay, Masood Akhtar, Spectro-Magnetic and Antimicrobial Studies on some 3d Metal Complexes with Ethylenedianil of Ortho-Hydroxyphenylglyoxal, American Journal of Applied Chemistry. Vol. 2, No. 1, 2014, pp. 15-18. doi: 10.11648/j.ajac.20140201.14
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